![]() The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, ![]() Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. Revision of the values of the heats of formation of normal alcohols,Ĭhem. Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages, Heats of combustion, formation, and isomerization of nineteen alkanols, Heats of formation of propellant compounds (U), Rpt. Go To: Top, Condensed phase thermochemistry data, Notes ![]() DHĬonstant pressure heat capacity of solid C p,solid (J/mol*K) DHĬonstant pressure heat capacity of liquid C p,liquid (J/mol*K) DHĮxtrapolation below 90 K, 40.75 J/mol*K. See Rossini, 1934 Corresponding Δ fHº liquid = -239.5 kJ/mol (simple calculation by NIST no Washburn corrections) ALSĬorresponding Δ fHº liquid = -238.7 kJ/mol (simple calculation by NIST no Washburn corrections) ALSĬorresponding Δ fHº liquid = -238.83 kJ/mol (simple calculation by NIST no Washburn corrections) ALSĬorresponding Δ fHº liquid = -250.1 kJ/mol (simple calculation by NIST no Washburn corrections) ALSĪt 291 K Corresponding Δ fHº liquid = -251.34 kJ/mol (simple calculation by NIST no Washburn corrections) ALSĮxtrapolation below 90 K, 34.3 J/mol*K. Reanalyzed by Cox and Pilcher, 1970, Original value = -238.5 ± 0.2 kJ/mol ALS Secretary of Commerce on behalf of the U.S.A.ĪLS - Hussein Y. Your institution may already be a subscriber.įollow the links above to find out more about the dataīy the U.S. With the development of data collections included in The purpose of the fee is to recover costs associated NIST subscription sites provide data under theĭata Program, but require an annual fee to access.
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YouTube Music Premium makes it easy to add your own music to its system from your computer. The app also pushes playlists made by other users in a section called “From the Community.” Engaged listeners with a point of view are taking the time to make public playlists, and there’s always something interesting to either provoke you or bring a bit of joy. There are no dates attached to albums, they’re not in release order and the Led Zeppelin artist page includes tribute albums by other artists, and the kind of cut-rate cover versions that are uploaded by opportunists looking to confuse inexperienced listeners and generate a few random plays. Music search is an unqualified black hole if you’re not already familiar with the artist’s work. It’s not a playlist, but a version of the homepage that includes songs that YouTube Music thinks fit that mood. There’s a powerful algorithm at work here and it’s impossible not to be impressed.īuttons at the top of the app generate music to match moods like Relax, Workout, Energize, Commute, and Focus. I’m also sure I’ve never played nearly all those songs on YouTube. There are 100 songs on the list and dozens that I already love. Sure, I might wish now that I’d been a bit more careful with what I shared over the years, but the My Supermix playlist that greeted me when I logged into the app is just truly spectacular. High-resolution music requires more bandwidth, which costs more money for the streaming service to license and stream. That High setting might be fine for many, but it’s not competitive with what’s on offer from Apple Music, Tidal, Qobuz, or Amazon Music Unlimited. The only reason anyone should consider any setting other than High would be that their ISP imposes a data cap. YouTube Music Premium gives you control over your streaming quality, but the options are limited to High (256Kbps), Normal (128Kbps), and Low (4Kbps). From the home page, tap on your avatar in the top-right corner. Streaming quality on YouTube Music Premium Start by downloading and then opening the YouTube Music app on your Android device. There’s an ad-supported free version of YouTube Music that gives access to much more on-demand music than you’ll get from the free versions of Spotify or Amazon Music. If you’re committed to another music streamer, but you watch a lot of YouTube videos, you might want to consider YouTube Premium just to kill those endless advertisements. If you choose YouTube Music Premium as your music service, then the extra couple of bucks a month for YouTube Premium is a no-brainer. You might think that’s a high price for YouTube Premium but, if you’re the kind of person who watches a lot of YouTube video, it’s a huge difference maker. ![]() The collection included adding Live Captions to iOS devices and making Siri’s response time adjustable for those with speech impairments. Apple unveiled a range of new and upgraded accessibility features for its devices this week. Initially published on The Limping Chicken on. How I wish I could use that adjective to describe my experience with the Pixel 6 Pro and Live Transcribe as a whole. There are no limits to Recorder, and its accuracy is impressive. Granted, rival applications such as Otter offer some respite for the journalists who hate transcriptions, but that only covers you on the free plan for 30 minutes. There is, however, one app I’ll look to use even when my SIM card is back in the reassuring confines of my iPhone, and that’s Recorder. ![]() I should mention that I was offered the opportunity to speak to the Google employee responsible for the Live Transcribe feature – and I would have asked him about the difference between Live Transcribe and automatic captions, and whether they use the same technology – but I am yet to be given a time for an interview. There’s no denying that for the longer, uncaptioned YouTube videos where automatic captions fail, Live Captions offer a sufficient last resort. Where this technology excelled for me, though, was in the form of Live Captions, capable of transcribing media playing out on the phone. I have no doubt there could be greater benefits for profoundly deaf individuals, however. I soon learned it was better for the conversations which are closer to the microphone – an obvious and fair technical requirement which I’ll grant – but for Deaf people like me with residual hearing, it’s often the case that our hearing is somewhat dependant on proximity to the source of the sound. It failed, instead choosing to inform me there was wind in the background when listening out for the tube announcement, and that there may have been a crowd nattering in the foyer. I was hoping the tech – designed with the help of Gallaudet University – would do what my (and many other) hearing aids could not, and make out a single voice among the background noise. As an aside, it would also fail to transcribe mobile calls, as described.Īnd know that I say this as an individual who acknowledges and brushes aside his Apple bias when writing this. I was making several train journeys with inaccessible tannoy announcements, and when in the welcoming walls of a theatre foyer, it was hard to hear the call for the audience to take their seats when it was drowned out by the social chatter of others.ĭisappointingly, Live Transcribe failed in both of these situations. The areas in which I could supposedly use the feature are endless, and over the course of a handful of days testing out the tech, many circumstances presented themselves. Speaking of Live Transcribe, let’s finally talk about the feature which led to Google kindly sending me the Pixel in the first place. Instead, I ended up opting for a menu which lingers on the right side of my screen, next to Live Transcribe – one which ultimately requires more buttons to perform the simple act of turning off a phone than one would typically expect. You have to press down on the power and volume button at the same time, and maybe it’s my dyspraxia or declining motor abilities revealing itself here, but it’s impossible to apply the right pressure on both buttons from one finger or thumb alone. The downsides – of which there are, tragically, many – include an oversensitive fingerprint scanner which fails to recognise your index finger more times than it does, a disorientating Maps app which doesn’t completely take you to your desired location, and a power off setting which is far from convenient. My long-term commitment, the iPhone, has the edge in that regard (Android comes with a slight blur on its viewfinder), but its Motion settings and 360 degree settings are unique to its hardware. First impressions were strong, as I admired its huge screen which slightly wraps around the sides, and its camera capabilities. The invitation to try out these features on the Google Pixel 6 Pro came just a few days before the start of this year’s Deaf Awareness Week, and I received the phone slap bang in the middle of it. For those wishing to invest in Google’s Android phones, there’s similar tools: Live Transcribe and Live Caption. Just how good are Google’s captioning capabilities? Well, we’ve all forayed onto YouTube and depended on automatic captions to understand the bare minimum, but even that automatic speech recognition technology – while it has improved over time – leaves a lot to be desired. ![]() You might be happy with using Ctrl+c to copy and Ctrl+v to paste in your plain old editor. With every Key you saved keeps you a key away from getting Carpel Tunnels and RSI. So, switching to Vim doesn't just improve your productivity, it take care of your health too. Imagine all the keystrokes you save per day, per year. So you see, Vim sticks to its philosophy of making you productive. Similarly no more Ctrl + c and Ctrl + v to copy and paste. What does Z even mean in Ctrl + z? And how did that become synonymous to Undo? Also u for undo is so simple to remember. All you have to do is press dd and that sucker goes away.ĭidn't mean to delete it? No problem. Paste the copied text below the current lineįrom now on you don't have to awkwardly select the full line with your mouse to delete it. Working in Normal mode, you will see how everything you do get's easy in Vim. But anyway we will discuss more about the this in the next article. Once you get used to this you wouldn't want to use arrow keys anymore. But trust me when I say using h j k l speeds up you work flow a lot. There are a lot of people who use vim this way. If you are thinking to stick with the arrow keys instead of h j k l, it is fine. This following picture would make the idea clear. H moves the cursor left, l moves it right The reason why this came to be and the advantages of this will be apparent in the next article but for now let's see how this works. In Vim they will work the way you expect them to, but instead vim advises to use h. To move around the file in the window you might usually be using arrow keys. One of the main things you will be doing in this mode is moving around your document. You can get to Normal mode by pressing ESC from any other mode. Normal Mode is the mode you will be spending most of your time in. You won't be inserting any new text into the document in this mode. Normal mode is used for altering, deleting and formatting text. Normal mode is the default mode you will be in when you open Vim. But to keep things simple here 4 is the magic number for you and 4 is the answer to Life, Universe and Everything. That number keeps changing depending on who you're talking to because there are a few more modes that can technically be called sub-modes but some people insist on treating them as Seperate modes. So, let's take a look at them.īroadly speaking Vim has Four major modes of operation. Vim works a bit differently and Modes is one of the key things that makes vim different. One of the first things you have to realize while using Vim is that its not like your typical run of the mill text editor. This happens because of the infamous Vim modes. For example, if you type hello world you might observe that only world is displayed and hello is no where to be seen. If you have already tried to type something, you would observe that there is something shady going on here. Your Gvim or Mac Vim would look something like this. If you want to start off with gvim then open that instead. You can do that either by directly searching for Vim in your Search box or by typing vim in to your terminal. And, most importantly as the title of the article suggests, we will learn How to Exit Vim.įirst thing's first, You have to open Vim. We will learn about the various modes of operations in Vim. ![]() In this article we will experience Vim for the first time. Hopefully after watching Damian Conway's YouTube video given at the end of that article, you would agree. In the last article Introduction & Installation we have seen why Vim is the best and coolest editor ever. This series is going to put an end to all of that. So, even when someone is interested in learning about Vim, that infamous learning curve seem to be scaring them off. ![]() Vim though quite powerful, has a bad rep for being hard to learn and hard to get started with. These articles are written with a goal of helping out new Vim users by teaching the awesomeness of the Vim editor and there by extending the Vim community. This is the second article in the series titled, " Your First Lesson In Vim". Whitman ( 1985) and Young-mee Yu Cho ( 1988) argue for dialectal variation, mainly focusing on the fact that deleting consonants vary between Seoul Korean and Kyungsang Korean. Even though there has been an agreement on the obligatoriness of CCS in the isolation forms of nouns in Korean, not much analysis has recently been provided as to which consonant is deleted or preserved, except for research conducted over 30 years ago. However, this is not always the case for other clusters, such as /lk/, where C 1 /l/ is deleted, but C 2 /k/ is preserved (e.g. For example, for /ps/, it is always C 1 /p/ that is preserved, while C 2 /s/ is deleted (e.g. However, CCS seems inconsistent across clusters. In other words, tautosyllabic consonants that are adjacent to each other are ungrammatical, and thus simplification via deletion is motivated to resolve the illicit forms. 1 This is due to the language-specific phonotactic restriction that consonant clusters are not allowed either in onset or in coda in Korean. It also occurs when noun stems are followed by a consonant-initial suffix: for instance, /ka ps-to/ ‘price too’ and /ta lk-to/ ‘chicken too’ (1b). Kong-On Kim & Shibatani 1976): for example, /ka ps/ ‘price’ and /ta lk/ ‘chicken’ (1a). In Korean, mandatory consonant cluster simplification (CCS) occurs in the isolation forms of nouns (e.g. The problematic structures are resolved by different phonological strategies, such as consonant deletion or vowel epenthesis, in different languages (e.g. ![]() This study is significant, in that it sheds light on a blind spot in the discussions of variation in stem-final consonant clusters in Korean and provides a comprehensive analysis that connects consonant cluster simplification in isolation forms with conservative/innovative forms in inflected forms.Ĭonsonant clusters are universally more marked than simplex consonants in terms of syllable well-formedness. While the nature of the consonant cluster turned out to be a significant factor for variation in inflected forms, other factors (inflectional suffixes, speakers’ regional dialects, and gender) did not. Innovative forms in particular are accounted for in relation to consonant cluster simplification in isolation forms of nouns, following Kenstowicz’s (1996) Base-Identity effect. ![]() Results of a production experiment show that there is a stark dichotomy between the clusters that share the same feature (/ps/, /ks/, /lm/) and those that do not (/lp/, /lk/, /ls/): the former preferred conservative forms, whereas the latter favored innovative forms. When it comes to simplification, it has also been unclear which of C 1 or C 2 undergoes deletion, and why. However, there has been no study about dominant patterns across clusters: which consonant cluster is more prone to preservation or simplification when inflected. conservative), or simplified by deleting one of the two consonantal elements C 1 and C 2 (i.e. It is well-established that the Korean stem-final consonant clusters are either fully faithfully preserved (i.e. This study investigates how Korean stem-final consonant clusters /ps/, /ks/, /lp/, /lk/, /ls/, and /lm/ exhibit variation, when a vowel-initial inflectional suffix is attached to noun stems. ![]() Guests can enhance their waxing experience with European Wax Center's signature line of skin and beauty products and the convenience of online booking. Let us pamper you with hair wax services like our Brazilian wax, eyebrow, bikini, leg, upper lip, face, full body waxing, and more. The Largo, FL center offers hair removal and waxing services for men and women. 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The Polish Underfolders metal stock is not the most pleasant thing in the world to fire but one "gets used to it" and for the coolness factor you really can't beat the ability to fold the stock under and turn the AK in a Pseudo AK Pistol. The polish tends to be around $100 more than the Yugo M70, not sure why maybe the chrome lined barrel. Both take the 30 round mags by default, both have the extreme reliability afforded to them by the Russian AK design. The Yugo M70 also has a built in rpg launcher feature. The Polish underfolder is said to have a better "fit" meaning the peices fit together better, but it also has a thinner receiver. ![]() The polish underfolder has a chrome lined barrel and this is helpful because most 7.62x39mm ammo is Russian made and most Russian made ammo is corrosive, especially the surplus stuff. It's most comparable to the Yugo Underfolder with a few specific differences. The under-folders are meant to tuck up into a small space so that the paratroopers can jump and land without injuring themselves, others, or the weapon, it then folds into a full size AK-47 with a thin frame stock. The Polish Underfolder AK-47 is Poland's take on the paratrooper style AK. In nursing homes, that changes a little bit. In acute care hospital settings, we recommend that contact precautions, which include gloves and gown, that health care providers ensure they're performing the appropriate hand hygiene, and that they have dedicated patient care equipment. When we do admission screening, we're able to have the facility place the patient or resident (depending on what facility type it is), if they screen positive for C auris, we recommend that those patients are placed on the appropriate transmission-based precautions. We know that asymptomatic colonization can also lead to a silent spread within a health care facility, often undetected, and so we see these larger outbreaks of C auris. If we do asymptomatic colonization, we're able to detect when a patient with C auris is not showing those signs or symptoms. Admission screening is important because we are able to identify patients or residents coming from long-term care facilities who are, as Megan indicated, asymptomatically colonized with C auris. Rankin, PhD, MPH: There are many different infection control measures that can work and beyond the basics, I want to focus on 2 primary key points that we often recommend to our health care facilities for seeing C auris, and 1 of them is admission screening. ICT: What can infection preventionists and environmental hygiene specialists do to help prevent this pathogen?ĭanielle A. It's difficult because no symptoms specifically point to C auris it's similar to infections caused by other pathogens. And if you have a wound infection from C auris, you might see redness, swelling, and drainage. If you have a bloodstream infection, you might have a fever or sepsis. However, it's often similar to infections caused by bacteria and viruses. Megan Lyman, MD: There aren't any specific signs or symptoms for C auris, which depends on the body site of where the infections are occurring. ICT: We hear about C auris in the news, but how do you recognize it? What are the symptoms? What do you see? This installment is the second in a series. Rankin, PhD, MPH, health scientist, Division of Healthcare Quality and Promotion, Prevention and Response Branch, Antimicrobial-Resistance Team, CDC. ![]() Infection Control Today® ( ICT ®), along with our colleague Chris Spivey, editorial director for Pharmaceutical Technology, Pharmaceutical Technology Europe, and BioPharm International, reached out for answers from Megan Lyman, MD, medical officer, Mycotic Diseases Branch, CDC, and Danielle A. What specific measures should IPs and EVS take to address this issue? Preventing the spread of Candida auris ( C auris) requires the efforts of not just infection preventionists (IPs) and environmental hygiene services (EVS), but also the entire facility or community. |
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